If you try to open %windir%\system32 folder with a 32 bit program, Windows will redirect you to %windir%\SysWOW64 folder.
For access the real system32 folder: define favorite folder %windir%\sysnative (e.g. c:\windows\sysnative) and open the folder. You are in system32 folder now.
How to access %windir%\system32 folder on Windows 7 64 bit
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